The amplification of solar extremes poses significant risks to Africa's energy infrastructure. Regions like WAPP and CAPP are particularly vulnerable, with synchronized low-output events threatening grid stability and increasing the likelihood of widespread power outages. The study highlights that countries heavily reliant on solar energy, such as Nigeria and Burkina Faso, face heightened risks due to their exposure to dust-driven radiative losses and thermal inefficiencies. In contrast, regions like the Southern African Power Pool (SAPP) exhibit greater resilience due to their diverse climatic conditions and energy portfolios. However, even resilient regions may face challenges as climate change exacerbates thermal stress, reducing the efficiency of solar panels and increasing energy demand for cooling.